Archive for January, 2009

Deep Well Injection

What is Deepwell Injection? Why do companies rely on this process to dispose of waste liquid materials rather that being a good corporate citizen? Quite simply, companies see this method of disposal as a  philosophy of “Out of sight, Out of mind” and they do not have any responsibility for the materials sent hunderds to thousands of feet under the earths surface. That is unless the earth regurgitates the materials like happened at Love Canal and the people living in the immediate area start law suits and petitioning the EPA to make the company responsible for their actions. Deepwell injection is at best a short term solution to a long term problem. Does this sound familiar. Its how business operates in the United States. Why not solve the problem by recycling the liquid wastes, recovering the acids and materials contained in the acids and making usable products from each material.

For instance, in the case of Ferrous Chloride, the Hydrochloric acid can be recovered and nano magnetic materials made from the iron contained in the Ferrous Chloride.

Following is a good description of Deepwell Injection coupled with a schematic of the earths structure. AK Steel hopes that their disposal of Ferrous Chloride will be contained at a depth of approximately 2500 feet, approximately 2000 feet below the local ground water table. It remains to be seen whether AK Steel will be a good corporate citizen and perform the testing and monitoring required by the EPA Exemption.

Deepwell Injection…

Description… Deep well injection is a liquid waste disposal technology. This alternative uses injection wells to place treated or untreated liquid waste into geologic formations that have no potential to allow migration of contaminants into potential potable water aquifers.A typical injection well consists of concentric pipes, which extend several thousand feet down from the surface level into highly saline, permeable injection zones that are confined vertically by impermeable strata. The outermost pipe or surface casing, extends below the base of any underground sources of drinking water (USDW) and is cemented back to the surface to prevent contamination of the USDW. Directly inside the surface casing is a long string casing that extends to and sometimes into the injection zone. This casing is filled in with cement all the way back to the surface in order to seal off the injected waste from the formations above the injection zone back to the surface. The casing provides a seal between the wastes in the injection zone and the upper formations. The waste is injected through the injection tubing inside the long string casing either through perforations in the long string or in the open hole below the bottom of the long string. The space between the string casing and the injection tube, called the annulus, is filled with an inert, pressurized fluid, and is sealed at the bottom by a removable packer preventing injected wastewater from backing up into the annulus.
Applicability and Limitations… The target contaminant groups for deep well injection are VOCs, SVOCs, fuels, explosives, and pesticides. However, existing permitted deep well injection facilities are limited to a narrow range of specific wastes. Success at expanding existing permits to manage hazardous wastes seems unlikely. Factors that may limit the applicability and effectiveness of these processes include ;

  • Injection will not be used for hazardous waste disposal in any areas where seismic activity could potentially occur.
  • Injected wastes must be compatible with the mechanical components of the injection well system and the natural formation water. The waste generator may be required to perform physical, chemical, biological, or thermal treatment for removal of various contaminants or constituents from the waste to modify the physical and chemical character of the waste to assure compatibility.
  • High concentrations of suspended solids (typically >2 ppm) can lead to plugging of the injection interval.
  • Corrosive media may react with the injection well components, with injection zone formation, or with confining strata with very undesirable results. Wastes should be neutralized.
  • High iron concentrations may result in fouling when conditions alter the valence state and convert soluble to insoluble species.
  • Organic carbon may serve as an energy source for indigenous or injected bacteria resulting in rapid population growth and subsequent fouling.
  • Waste streams containing organic contaminants above their solubility limits may require pretreatment before injection into a well.
  • Site assessment and aquifer characterization are required to determine suitability of site for wastewater injection.
  • Extensive assessments must be completed prior to receiving approval from regulatory authority.